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91.
In order to characterize the pressure-induced decomposition of ringwoodite (γ-Mg2SiO4), the topological analysis of the electron density ρ(r), based upon the theory of atoms in molecules (AIM) developed by Bader in the framework of the catastrophe theory, has been performed. Calculations have been carried out by means of the ab initio CRYSTAL09 code at the HF/DFT level, using Hamiltonians based on the Becke- LYP scheme containing hybrid Hartree–Fock/density functional exchange–correlation terms. The equation of state at 0 K has been constructed for the three phases involved in the post-spinel phase transition (ringwoodite → Mg-perovskite + periclase) occurring at the transition zone–lower mantel boundary. The topological results show that the decomposition of the ringwoodite at high pressures is caused by a conflict catastrophe. Furthermore, topological evidences of the central role played by the oxygen atoms to facilitate the pressure-induced ringwoodite decomposition and the subsequent phase transition have been noticed.  相似文献   
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93.
This study surveys the most recent projections of future climate change provided by 20 Atmospheric-Ocean General Circulation Models (AOGCMs) participating in the Coupled Model Intercomparison Project 3 (CMIP3) with focus on the Italian region and in particular on the Italian Greater Alpine Region (GAR). We analyze historical and future simulations of monthly-mean surface air temperature (T) and total precipitation (P). We first compare simulated T and P from the AOGCMs with observations over Italy for the period 1951–2000, using bias indices as a metric for estimating the performance of each model. Using these bias indices and different ensemble averaging methods, we construct ensemble mean projections of future climate change over these regions under three different IPCC emission scenarios (A2, A1B, and B1). We find that the emissions pathway chosen has a greater impact on future simulated climate than the criteria used to obtain the ensemble means. Across all averaging methods and emission scenarios, the models project annual mean increase in T of 2–4°C over the period 1990–2100, with more pronounced increases in summer and warming of similar magnitude at high and low elevations areas (according to a threshold of 400 m). The models project decreases in annual-mean P over this same time period both over the Italian and GAR regions. This decrease is more pronounced over Italy, since a small increase in precipitation over the GAR is projected in the winter season.  相似文献   
94.
Regional variability of climate change hot-spots in East Asia   总被引:2,自引:0,他引:2  
The regional climate change index (RCCI) is employed to investigate hot-spots under 21st century global warming over East Asia. The RCCI is calculated on a 1-degree resolution grid from the ensemble of CMIP3 simulations for the B1, A1B, and A2 IPCC emission scenarios. The RCCI over East Asia exhibits marked sub-regional variability. Five sub-regional hot-spots are identified over the area of investigation: three in the northern regions (Northeast China, Mongolia, and Northwest China), one in eastern China, and one over the Tibetan Plateau. Contributions from different factors to the RCCI are discussed for the sub-regions. Analysis of the temporal evolution of the hot-spots throughout the 21st century shows different speeds of response time to global warming for the different sub-regions. Hot-spots firstly emerge in Northwest China and Mongolia. The Northeast China hot-spot becomes evident by the mid of the 21st century and it is the most prominent by the end of the century. While hot-spots are generally evident in all the 5 sub-regions for the A1B and A2 scenarios, only the Tibetan Plateau and Northwest China hot-spots emerge in the B1 scenario, which has the lowest greenhouse gas (GHG) concentrations. Our analysis indicates that sub-regional hot-spots show a rather complex spatial and temporal dependency on the GHG concentration and on the different factors contributing to the RCCI.  相似文献   
95.
In the framework of the VECTOR DIVCOST Project, a 2-year investigation was started in 2006, with the aim of testing the sensibility of microbial parameters to environmental changes and of assessing whether they can provide information about functional changes in the carbon cycle. The investigation was performed in the surface waters of two small brackish ponds (Ganzirri and Faro), located in the Cape Peloro transitional area (Sicily, Italy). The seasonal changes in both the microbial compartment [bacterioplankton, vibrios, exoenzymatic hydrolysis of proteins and polysaccharides, bacterial secondary production (HBP) and community respiration] and the trophic state of suspended matter [total suspended matter (TSM), particulate organic carbon (POC), particulate organic nitrogen (PON), C/N] were analysed in relation to the hydrological characteristics [temperature, salinity, oxygen, fluorescence, NH4, NO2, NO3, PO4]. Despite marked differences in the nutritional input and the diversification in both carbon budget and trophic level, the two ponds show similar trends in many of the investigated factors, hardly influenced by seasonal variations. Temporally coupled trends were observed for some parameters (enzyme activities, vibrios abundances, respiratory activity), whereas others (POC, PON, heterotrophic bacterial production, bacterioplankton) showed a seasonal shift between the two lakes. The different behaviour found for the some biotic parameters suggests that their response to environmental conditions may be modulated differently between the two lakes, which, despite their spatial proximity and reciprocal connection, do not always show contemporaneous functional processes.  相似文献   
96.
97.
Future changes in tropical cyclone(TC)activity over the western North Pacific(WNP)under the representative concentration pathway RCP4.5 are investigated based on a set of 21 st century climate change simulations over East Asia with the regional climate model RegCM4 driven by five global models.The RegCM4 reproduces the major features of the observed TC activity over the region in the present-day period of 1986-2005,although with the underestimation of the number of TC genesis and intensity.A low number of TCs making landfall over China is also simulated.By the end of the 21st century(2079-98),the annual mean frequency of TC genesis and occurrence is projected to increase over the WNP by16%and 10%,respectively.The increase in frequency of TC occurrence is in good agreement among the simulations,with the largest increase over the ocean surrounding Taiwan Island and to the south of Japan.The TCs tend to be stronger in the future compared to the present-day period of 1986-2005,with a large increase in the frequency of strong TCs.In addition,more TCs landings are projected over most of the China coast,with an increase of~18%over the whole Chinese territory.  相似文献   
98.
Global navigation satellite system (GNSS) ambiguity resolution is the process of resolving the unknown cycle ambiguities of the carrier phase data as integers. The sole purpose of ambiguity resolution is to use the integer ambiguity constraints as a means of improving significantly on the precision of the remaining GNSS model parameters. In this contribution, we consider the problem of ambiguity resolution for GNSS attitude determination. We analyse the performance of a new ambiguity resolution method for GNSS attitude determination. As it will be shown, this method provides a numerically efficient, highly reliable and robust solution of the nonlinearly constrained integer least-squares GNSS compass estimators. The analyses have been done by means of a unique set of extensive experimental tests, using simulated as well as actual GNSS data and using receivers of different manufacturers and type as well as different platforms. The executed field tests cover two static land experiments, one in the Netherlands and one in Australia, and two dynamic experiments, a low-dynamics vessel experiment and high-dynamics aircraft experiment. In our analyses, we focus on stand-alone, unaided, single-frequency, single-epoch attitude determination, as this is the most challenging case of GNSS compass processing.  相似文献   
99.
Observations of water surface elevation (WSE) and bathymetry of the lagoons and cenotes of the Yucatán Peninsula (YP) in southeast Mexico are of hydrogeological interest. Observations of WSE (orthometric water height above mean sea level, amsl) are required to inform hydrological models, to estimate hydraulic gradients and groundwater flow directions. Measurements of bathymetry and water depth (elevation of the water surface above the bed of the water body) improve current knowledge on how lagoons and cenotes connect through the complicated submerged cave systems and the diffuse flow in the rock matrix. A novel approach is described that uses unmanned aerial vehicles (UAVs) to monitor WSE and bathymetry of the inland water bodies on the YP. UAV-borne WSE observations were retrieved using a radar and a global navigation satellite system on-board a multi-copter platform. Water depth was measured using a tethered floating sonar controlled by the UAV. This sonar provides depth measurements also in deep and turbid water. Bathymetry (wet-bed elevation amsl) can be computed by subtracting water depth from WSE. Accuracy of the WSE measurements is better than 5–7 cm and accuracy of the water depth measurements is estimated to be ~3.8% of the actual water depth. The technology provided accurate measurements of WSE and bathymetry in both wetlands (lagoons) and cenotes. UAV-borne technology is shown to be a more flexible and lower cost alternative to manned aircrafts. UAVs allow monitoring of remote areas located in the jungle of the YP, which are difficult to access by human operators.  相似文献   
100.
 We compared regional biases and transient doubled CO2 sensitivities of nine coupled atmosphere-ocean general circulation models (GCMs) from six international climate modeling groups. We evaluated biases and responses in winter and summer surface air temperatures and precipitation for seven subcontinental regions, including those in the 1990 Intergovernmental Panel on Climate Change (IPCC) Scientific Assessment. Regional biases were large and exceeded the variance among four climatological datasets, indicating that model biases were not primarily due to uncertainty in observations. Model responses to altered greenhouse forcing were substantial (average temperature change=2.7±0.9 °C, range of precipitation change =−35 to +120% of control). While coupled models include more climate system feedbacks than earlier GCMs implemented with mixed-layer ocean models, inclusion of a dynamic ocean alone did not improve simulation of long-term mean climatology nor increase convergence among model responses to altered greenhouse gas forcing. On the other hand, features of some of the coupled models including flux adjustment (which may have simply masked simulation errors), high horizontal resolution, and estimation of screen height temperature contributed to improved simulation of long-term surface climate. The large range of model responses was partly accounted for by inconsistencies in forcing scenarios and transient-simulation averaging periods. Nonetheless, the models generally had greater agreement in their sensitivities than their controls did with observations. This suggests that consistent, large-scale response features from an ensemble of model sensitivity experiments may not depend on details of their representation of present-day climate. Received: 9 September 1996 / Revised: 31 July 1997  相似文献   
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